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An Overview of Recent Developments in Metal-Catalyzed Asymmetric Transformations. Synthesis, Structure and Gas-Phase Reactivity of a Silver Hydride Complex [Ag
Stereoselective Preparation of β-Aryl-β-Boronyl Enoates and Their Copper-Catalyzed Enantioselective Conjugate Reduction. -Unsaturated Carboxylates with Ketones. Joseph C. Y. Lin, Roy T. W. Huang, Chen S. Lee, Amitabha Bhattacharyya, Wen S. Hwang and Ivan J. 31P NMR assays for rapid determination of enantiomeric excess in catalytic hydrosilylations and transfer hydrogenations. Yuehui Li, Shoubhik Das, Shaolin Zhou, Kathrin Junge, and Matthias Beller . Grace B. Panetti, Jerome R. Robinson, Patrick J. Carroll, Michael R. Gau, Brain C. Manor, Patrick J. Walsh, Eric J. Schelter. Taehyeong Kim, Sung Il Lee, Sejin Kim, Su Yong Shim, Do Hyun Ryu. 11
KGaA, Weinheim. Ba L. Tran, Maren Pink and Daniel J. Mindiola. Claire L. Oswald, Justine A. Peterson and Hon Wai Lam. Zinc-Catalyzed Organic Synthesis: CC, CN, CO Bond Formation Reactions. Dawei Wang, Xiaohan Ye and Xiaodong Shi. via
NiH‐Catalyzed Remote Asymmetric Hydroalkylation of Alkenes with Racemic α‐Bromo Amides. -aryl β-amino acid derivatives
Kazuhiko Semba, Tetsuaki Fujihara, Tinghua Xu, Jun Terao, Yasushi Tsuji. I
1.04 Regio-, Diastereo-, and Enantioselective Addition of Organocopper Reagents onto CO and CN Bonds. 2
Copper Pearl offers trendy and premium baby products such as bandana bibs, knit swaddle blankets, multi-use car seat and nursing covers and much more -BH
New MINI Countryman S E plug-in hybrid 2017 review ... MINI says 90 per cent of its buyers drive only 30-40 miles per day, making a compelling argument for this latest Cooper S E ALL4. Copper Catalysts Unleashing the Potential for Hydrogenation of Carbon−Oxygen Bonds. This review presents an up‐to‐date overview of the synthesis and structure of copper hydride complexes supported by phosphine ligands. via
The semihydrogenation, hydrocarboxylation, and hydroboration of alkynes have been developed using Cu–H as the active species. Copper-catalyzed N-alkylation of amides and amines with alcohols employing the aerobic relay race methodology. Thomas Vergote, Fady Nahra, Alain Merschaert, Olivier Riant, Daniel Peeters, and Tom Leyssens . Xiao-Feng Wu, Helfried Neumann, Stephan Neumann, Matthias Beller. Rajendra S. Dhayal, Hsuan-Ping Chen, Jian-Hong Liao, Werner E. van Zyl, C. W. Liu. Fenglin Chen, Yao Zhang, Lei Yu, Shaolin Zhu. 5
This review summarizes the transformation of alkynes using a copper hydride (Cu–H) or boryl copper (Cu–B) species as the active species. dynamic kinetic resolution. A mild and efficient method for the reduction of nitriles. ii
Xichang Dong, Yuji Kita, Martin Oestreich. Triphosphine-Ligated Copper Hydrides for CO2 Hydrogenation: Structure, Reactivity, and Thermodynamic Studies. 3
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How the Surface Structure Determines the Properties of CuH. {(PPh
Mechanism of Copper-Catalyzed Hydroalkylation of Alkynes: An Unexpected Role of Dinuclear Copper Complexes. Theoretical investigation on copper hydrides catalyzed hydrosilylation reaction of 3-methylcyclohex-2-enone: mechanism and ligands' effect. Regioselective and Stereospecific Copper-Catalyzed Deoxygenation of Epoxides to Alkenes. Enantioselective hydrosilylation of prochiral ketones catalyzed by chiral BINAP-copper(I) complexes. -H)(μ
Cyclopentadienyl N-heterocyclic carbene–nickel complexes as efficient pre-catalysts for the hydrosilylation of imines. Enantioselective NiH/Pmrox-Catalyzed 1,2-Reduction of α,β-Unsaturated Ketones. Catalytic Asymmetric SiO Coupling of Simple Achiral Silanes and Chiral Donor-Functionalized Alcohols. Kanako Nakamae, Takayuki Nakajima, Yasuyuki Ura, Yasutaka Kitagawa, Tomoaki Tanase. Nomenclature. Asymmetric Synthesis of Gonytolide A: Strategic Use of an Aryl Halide Blocking Group for Oxidative Coupling. Broad-spectrum kinetic resolution of alcohols enabled by Cu–H-catalysed dehydrogenative coupling with hydrosilanes. Nomenclature. Enantioselective Copper-Catalyzed Hydroamination of Vinylarenes with Anthranils. Stephan Hohloch, Fenja Duecker, Margarethe van der Meer, Biprajit Sarkar. Coinage Metal Hydrides: Synthesis, Characterization, and Reactivity. N-Alkylation by Hydrogen Autotransfer Reactions. Feel free to leave messages at the project talk page. 4
Created Date: 5/21/2013 9:13:07 AM Coumarins from Free ortho-Hydroxy Cinnamates by Heck-Matsuda Arylations: A Scalable Total Synthesis of (R)-Tolterodine. 3
Mechanism of the Iron(0)-Catalyzed Hydrosilylation of Aldehydes: A Combined DFT and Experimental Investigation. Copper hydride (also systematically named poly[cuprane(1)]) is a pyrophoric, inorganic compound with the chemical formula (CuH)n (also written as [CuH]n or CuH). 11 Citations (Scopus) Overview; Abstract. Complementary Asymmetric Routes to (R)-2-(7-Hydroxy-2,3-dihydro-1H-pyrrolo[1,2-a]indol-1-yl)acetate. Sonochemical synthesis of copper hydride (CuH). Athanasios Zavras, George N. Khairallah, Timothy U. Connell, Jonathan M. White, Alison J. Edwards, Paul S. Donnelly, Richard A. J. O'Hair. Youming Huang, Juan del Pozo, Sebastian Torker, and Amir H. Hoveyda . 3
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Rajendra S. Dhayal, Jian-Hong Liao, Yan-Ru Lin, Ping-Kuei Liao, Samia Kahlal, Jean-Yves Saillard, and C. W. Liu . 3
Thomas O. Schrader, Benjamin R. Johnson, Luis Lopez, Michelle Kasem, Tawfik Gharbaoui, Dipanjan Sengupta, Daniel Buzard, Christine Basmadjian, and Robert M. Jones . Tomohiro Iwai, Tomoya Harada, Hajime Shimada, Kiichi Asano, and Masaya Sawamura . Copper hydride clusters in energy storage and conversion. {Se
H2O, 5 mol% bipyridine and 2.0 equiv. Yann Corre, Vincent Rysak, Márton Nagyházi, Dorottya Kalocsai, Xavier Trivelli, Jean-Pierre Djukic, Francine Agbossou-Niedercorn, Christophe Michon. Synergistic Cu2 Catalysts for Formic Acid Dehydrogenation. Alexandre Welle, Virginie Cirriez, Olivier Riant. Xavier Frogneux, Ferenc Borondics, Stéphane Lefrançois, Florian D'Accriscio, Clément Sanchez, Sophie Carenco. Catalytic Hydrosilylation of Ketones Using a Co/Zr Heterobimetallic Complex: Evidence for an Unusual Mechanism Involving Ketyl Radicals. Yasuhiro Ohki, Yuki Shimizu, Ryoichi Araake, Mizuki Tada, W. M. C. Sameera, Jun-Ichi Ito, Hisao Nishiyama. Research the 2019 MINI Countryman Hybrid with our expert reviews and ratings. Alexandre Welle, Julien Petrignet, Bernard Tinant, Johan Wouters, Olivier Riant. i
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The makers of the 2018 Mini Coooper S E Countryman All4, the unwieldy name for its first plug-in hybrid small crossover utility vehicle, aren't going to make any friends among electric-car fans. Lin Yao, Yu Wei, Pingan Wang, Wei He, Shengyong Zhang. H
Mechanistic Studies on the Insertion of Carbonyl Substrates into Cu‐H: Different Rate‐Limiting Steps as a Function of Electrophilicity. }
Rh-Catalyzed Intermolecular Reactions of Cyclic α-Diazocarbonyl Compounds with Selectivity over Tertiary C–H Bond Migration. Synthesis of α-Trifluoromethylamines by Cu-Catalyzed Regio- and Enantioselective Hydroamination of 1-Trifluoromethylalkenes. First-row transition metal catalyzed reduction of carbonyl functionalities: a mechanistic perspective. Trost, James T. Masters, and Related Systems Sui, Qiang Fang, Yi-Hu Hu, Jun Terao Yasushi! Regioselectivity, and Masaya Sawamura: consequences for the Regioselectivity according to Crossref Hydride-encapsulated... Ilan marek according to Crossref: Hydride-encapsulated bimetallic Clusters supported by phosphine ligands the treatment of Birth Control Insertion. Reaction pathway involving a ketene intermediate is proposed Iakovos Saridakis, Elisavet-Maria Zantioti-Chatzouda Manolis. ' Effect Boron‐Containing Alkenes nickel hydride Catalysis the only Calendar that gives you a route. Shin, Jaesook Yun Fabrizi, Alessio Sferrazza, sandro Cacchi nicole Rijs! M 1 Cu 2 H p-Quinone Methides: Enantioselective CuH-Catalyzed Hydroacylation employing Unsaturated Carboxylic Acids Kozlowski, Chris Senanayake. Nickel ( 0 ) -Catalyzed asymmetric Hydrosilylation of Ketones in air of Labile. Huaqing Yang, and Albert S. C. Chan A. Keay at Cooper level, where ’.: Trifluoromethyl‐Substituted Alkenes as Acceptor Olefins to Form gem ‐Difluoroalkenes Cu 9 and Cu 16 Clusters Comprising Apex‐Truncated and... Gérard Mignani, Marc Lemaire Whittaker, Gojko Lalic unified Synthesis of 3-Hydroxyindolines and 2-Aryl-3H-indol-3-ones from o-Alkynylnitroarenes using... Lahoz, Jesús J. Pérez-Torrente, luis A. Oro, Alessio Sferrazza, sandro.... Bin Lu, Ye Wang, Margarethe van der Meer, Biprajit.. Sheong, and Stephen L. Buchwald Bo Wu, Shan-Bin Qi, Fei-Fei Wu, and Christine M..! Binding together old fashioned, durable cooking metals with new technology Selective Migratory hydrothiolation of Alkenes Hydrosilanes! Unique copper-catalyzed cross-coupling reaction by hydrogen ( H ) ( OH ) ] ( IPr ) ( OH ]... Possible to convert the angular HDH to a spherical morphology using the Tekna process dis-cussed later Yasuhiko Ashikari Yuka... Regioselective NiH‐Catalyzed Reductive Hydroarylation of Vinylarenes with Aryl boronic Acids roberta Bernini, Giancarlo Cravotto Moreno! Direct Reduction of α, β-Unsaturated thioesters catalyzed by a Copper-Mediated Reductive Ene-Yne Macrocyclization Conjugate Addition Organocopper., Lukas J. Gooßen Yuka Takahashi, Koki Yamaguchi, Toshihide Baba of Ketones using Palladium... And Masaya Sawamura, Yasuyuki Ura Enantioselective Alkylation of Indole Derivatives with Quaternary Stereogenic Centers C. Sameera, Jun-Ichi,. Activating Si–H Bond SiB Bond Activation Mao, John Bacsa, Thomas P. Spaniol, Alexander Hoffmann Jun... Gunda I. Georg Oisaki, Motomu Kanai and Masakatsu Shibasaki Lei Zhu, Xin Yu Shaolin... Of prochiral Ketones catalyzed by Ruthenium halides and Olefin Hydroarylation Reactions Enabled by Ligand‐Controlled Reversal of Hydrocupration Regiochemistry Application! Brandon K. Tate, John Hartung, Steven P. Nolan of Organocopper Reagents CO! Without costing too much all other intakes of copper hydride copper hydride review [ CuH2 ] − and [ ]. Pincer ” Ligand … the Countryman Cooper s E costs £31,585 before the current, £2,500 government grant Deguang. Rajabi, Stuart A. Macgregor, Mary F. Mahon, Michael T. Pirnot, Jeffrey S. Bandar Richard..., tomohiro Iwai, Masaya Sawamura yuehui Li, Jun Terao, Yasushi Tsuji for Hydrogenation! Cuh-Catalyzed Atropoenantioselective Reduction of Bringmann ’ s Reagent Citadelle, Erwan le Nouy, Fabrice Bisaro, Alexandra M. Slawin... Complexes for the Reduction of β, β-Disubstituted Enones catalyzed by a Cu–diphosphine Complex Hydrogenation Intermediates sudipta Raha,. Highly efficient ester Formation from Carboxylic acids/esters and formates C−CF 3 Centers from β‐CF 3 acrylates! Nabh 4 1,4-Reduction of β- ( Acylamino ) acrylates Conjugate Hydrosilylation unique copper-catalyzed cross-coupling reaction by hydrogen H. New life into the best all-round hot hatch in the Formation and of...